Sintesis dan Karakterisasi Senyawa Kompleks Diamminaperak(I) Klorida [Ag(NH₃)₂]Cl melalui Reaksi Koordinasi Ion Perak dengan Amonia (NH₃)
Keywords:
Diamminaperak(I), Ligan Amonia, Senyawa Kompleks, SintesisAbstract
Penelitian ini dilatarbelakangi oleh pentingnya pemahaman mekanisme pembentukan ikatan koordinasi pada senyawa kompleks logam, khususnya kompleks perak(I) dengan ligan amonia yang masih terbatas pada pembelajaran laboratorium sederhana. Penelitian ini bertujuan untuk mensintesis dan mengkarakterisasi senyawa kompleks diamminaperak(I) klorida [Ag(NH₃)₂]Cl. Penelitian dilakukan di Laboratorium Kimia Anorganik, Program Studi Kimia, Universitas Negeri Medan menggunakan metode eksperimen laboratorium. Teknik pengumpulan data dilakukan melalui observasi langsung terhadap perubahan fisika dan kimia selama proses reaksi, meliputi perubahan warna, terbentuknya endapan, dan kelarutan. Hasil penelitian menunjukkan terbentuknya endapan putih AgCl yang larut setelah penambahan NH₃ berlebih menghasilkan larutan bening sebagai indikasi terbentuknya kompleks [Ag(NH₃)₂]⁺. Kompleks yang dihasilkan memiliki bilangan koordinasi dua dengan geometri linear. Dengan demikian, sintesis kompleks berhasil dilakukan sesuai teori kimia koordinasi.
References
Ahmed, K. M. (2025). A review of coordination compounds : structure , stability , and biological signi fi cance. Reviews in Inorganic Chemistry, 45(1), 1–19. https://doi.org/10.1515/revic-2024-0035
Amanda, M. V., Salma, N., Azizah, N., Laili, N., & Indah, E. (2023). Sintesis Kloropentaamin Kobalt (III) Klorida dengan Reaksi Langsung. 3(6), 272–283. https://doi.org/10.17977/um067v3i6p272-283
Aydogan, S., Taha, M., Abdelraheem, O., Ali, B., & Boyrazli, M. (2025). Kinetics Study on the Leaching of Metallic Silver with Ammonium Carbonate as an Eco-Friendly Alternative for Cyanide. JOM, 77(7), 5622–5631. https://doi.org/10.1007/s11837-025-07424-w
Fadillah, N., & Sutiani, A. (2025). Jurnal Pendidikan dan Pembelajaran Kimia Development of an Acid-Base E-Module Based on Project-Based Learning ( PjBL ) Assisted by Canva Application. 14(1), 182–196. https://doi.org/10.23960/jppk.v14.i1.33538
Gouri, K. S., George, A., Srivastava, R., & Patel, V. (2026). Effect of electrochemical deposition method on the AgCl film generated on silver substrates.
Kang, G., Zhong, Y., Du, X., Shao, Z., Jiang, J., Wang, X., Li, W., Guo, S., Gao, L., Fang, Z., & Zheng, G. (2023). Materials & Design Low-temperature sintering of silver-ammonia complex organic composite ink shows high conductivity for humidity sensors. Materials & Design, 234(June), 112374. https://doi.org/10.1016/j.matdes.2023.112374
Kartika, A. S., & Fitria, J. D. (2023). Sintesis dan Karakterisasi Senyawa Kompleks Kloropentaaminakobalt (III) Klorida. 3(6), 264–271. https://doi.org/10.17977/um067v3i6p264-271
Marinova, P. E. (2025). Synthesis , Investigation , Biological Evaluation , and Application of Coordination Compounds with Schiff Base — A Review.
Mn, X., Re, T., & Complexes, A. (2023). Review on the Chemistry of [M(NH 3 ).
Nguyen, L. H., Tran, D. P., & Truong, T. N. (2022). Computational Study on the Nature of Bonding between Silver Ions and Nitrogen Ligands. https://doi.org/10.1021/acsomega.2c05707
Supriyanto, M. U. (2022). Sintesis Dan Karakterisasi Senyawa Kompleks dari Perak Stoikiometri 2 : 1. 2(3), 364–371. https://doi.org/10.17977/um067v2i5p364-371
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